C2H2 Lewis structure, Molecular Geometry, Hybridization & Bond angle (2024)

C2H2 is a chemical formula for Ethyne, a gaseous alkyne hydrocarbon. It has been used widely for welding and cutting purposes. This molecule is also known by the name Acetylene. The compound has a simple structure and is made up of two carbon atoms and two hydrogen atoms.

Name of moleculeEthyne ( C2H2)
No of Valence Electrons in the molecule10
Hybridization of C2H2sp hybridization
Bond Angles180°
Molecular Geometry of C2H2Linear

In this blog post, we will learn about the total number of valence electrons for C2H2, its Lewis Structure, Molecular Geometry, Shape and more.

Contents

C2H2 Valence electrons

The electrons present in the atoms’ outer shell are the ones that participate in bond formation with other atoms in the molecule. These electrons are known as the valence electrons. To draw a Lewis Structure of any molecule and understand the bond formation in any molecule, it is essential to know the total number of valence electrons.

Valence electrons in C2H2: Valence electrons of Carbon atom + Valence electrons of Carbon atom

The carbon atom has four valence electrons in its outer shell, but here as there are two Carbon atoms we will multiply the number by 2. Hence there are eight valence electrons for Carbon atoms.

A Hydrogen atom has one valence electron in its outer shell; we will multiply it by two as there are two Hydrogen atoms. So there are two valence electrons for Hydrogen atoms.

Valence electrons in C2H2: 8 + 2

= 10

There are ten valence electrons in C2H2 molecule.

C2H2 Lewis structure, Molecular Geometry, Hybridization & Bond angle (1)

C2H2 Lewis Structure

Lewis Structure of any molecule helps to know the arrangement of all atoms, their valence electrons, and the bond formation in the molecule. The electrons that participate in forming bonds are called bonding pairs of electrons while the ones that do not take part in any bond formation are called lone pairs or non-bonding pairs of electrons.

For C2H2 Lewis structure, we will first place both the Carbon atoms in the centre as it is less electronegative than the Hydrogen atoms. Here both the Carbon atoms take the central position, and the Hydrogen atoms are arranged around it.

If you look at the Hydrogen atoms, it only needs one valence electron to attain a stable structure. Here, both the Hydrogen atoms will share one valence electron of the Carbon atom and form a bond.

The octets of both the Hydrogen atoms are now complete, but Carbon atoms still don’t have a complete octet. To attain a stable structure, the Carbon atoms will share their remaining three valence electrons by forming a triple bond.

Note: A total of six valence electrons is used to form a triple bond between both the Carbon atoms.

In Lewis structure of C2H2, the octets of all the atoms are complete, and there are no lone pairs of electrons in the molecule.

C2H2 Lewis structure, Molecular Geometry, Hybridization & Bond angle (2)

C2H2 Molecular Geometry

The Lewis structure of C2H2 helps us understand the geometry of the molecule. All the atoms here lie in the same plane, and there is no asymmetry in the molecule. As all the atoms are arranged symmetrically in the same plane, C2H2 has a linear molecular geometry.

C2H2 Lewis structure, Molecular Geometry, Hybridization & Bond angle (3)

C2H2 Hybridization

To make it easier for you to understand, consider this molecule made up of two CH atoms. Carbon atom’s electron configuration in its ground state is 1s2 2s2 2p2, but when it is in its excited state, the electron from the 2s orbital moves to the 2pz orbital. This hybridized molecule accommodates the shared electron of the Hydrogen. The 1s orbital of the Hydrogen atom overlaps with the Carbon atom’s 2p orbital atom, making it an sp hybridization. There is the formation of one hybridized s and p orbital. This is the same for the other set of CH molecules too.

Carbon atoms form sigma bonds with each other when one sp orbital overlaps with the sp orbital of the other CH molecule. C-H bonds are created when the second sp orbital overalls with the 1s orbital of the Hydrogen atom. There are two-half filled 2p orbitals for each Carbon atom. These two orbitals form two pi bonds that result in the formation of triple bonds between carbon atoms.

Hence, the Carbon atom has sp hybridization in the C2H2 molecule.

C2H2 Bond Angles

All the atoms are arranged symmetrically as both the Carbon atoms form a single bond with Hydrogen atoms. The bond angle in C2H2 is 180 degrees.

C2H2 Shape

C2H2 has a linear shape given its molecular geometry is linear and all the atoms are arranged symmetrically.

Concluding Remarks

To summarize this article on C2H2 Lewis structure, we can say that,

  • There are ten valence electrons for Ethyne.
  • Carbon atom forms a single bond with one Hydrogen atom and a triple bond with another Carbon atom.
  • As all the valence electrons are used up in the structure, there are no unshared electrons.
  • It has sp hybridization with a bond angle of 180 degrees.
  • C2H2 is a linear molecule as the distribution of the atoms is symmetric in this molecule.

To find out about the polarity of C2H2, you can check out our detailed blog post on C2H2 polarity.

C2H2 Lewis structure, Molecular Geometry, Hybridization & Bond angle (2024)

FAQs

C2H2 Lewis structure, Molecular Geometry, Hybridization & Bond angle? ›

C2H2 is a tetratomic molecule made up of two distinct atoms that link in equal amounts. Furthermore, carbon bonds to carbon, giving acetylene a linear structure and a 180° bond angle.

What is the bond angle of C2H2 hybridization? ›

Due to the triple bond, the molecular geometry of C2H2 is linear, with a bond angle of 180°.

What is the bond structure of C2H2? ›

Structure of Ethyne Molecules

The ethyne molecule features a triple bond between two carbon atoms, each of which is singly bonded to one other hydrogen atom. It can be noted that all four atoms align in a straight line with bond angles of approximately 180o.

What is the shape bond angle and hybridization of C2H4? ›

C2H4 is an example of sp² hybridization, meaning one s orbital, and two p orbitals are mixed to give three sp² orbitals. Here, one 2p orbital does not change, and it will help form a pi bond. Each of the sp² carbon atoms has a trigonal planar geometry and an angle of 120o between the bonds.

Why is c2h2 sp2 hybridized? ›

The ethyne molecule is sp hybridised because it has one sigma and two carbon-carbon pi bonds. The carbon atom requires extra electrons to establish four bonds with hydrogen and other carbon atoms to create C2H2. As a result, one 2s2 pair is shifted to the 2pz orbital, which is now unoccupied.

How do you find the bond angle of hybridization? ›

A different ratio of s character and p character gives a different bond angle. For example, in sp2 hybridized orbitals (with ⅓ s character and ⅔ p character) the angle between bonds is 120°, whereas, for sp3 the angle is 109.5°. More p character results in a smaller bond angle.

What is the bond order for C2H2? ›

Examples. The bond order of the carbon-hydrogen bond in C2H2 (ethyne/acetylene) is 1 and that of the carbon-carbon bond is 3.

Is C2H2 a single double or triple bond? ›

Ethyne, C2H2, has a triple bond between the two carbon atoms. In the diagram each line represents one pair of shared electrons.

What is the hybridization of the carbon atoms in acetylene? ›

In the hybrid orbital picture of acetylene, both carbons are sp-hybridized.

What is the bond angle of C2H2? ›

C2H2 Bond Angles

Because both Carbon atoms establish a single bond with Hydrogen atoms, all of the atoms in C2H2 are organised symmetrically. In C2H2, the bond angle is 180 degrees.

What is the angle and shape of hybridization? ›

Basic shapes of Hybridization: Overview

In perfect Hybridization, the five shapes are linear, trigonal planar, tetrahedral, Trigonal planar, Trigonal by-Pyramidal, and octahedral. These shapes are formed by the hybridised orbitals. Four main types of orbitals carry different characteristics. They are s, p, d and f.

How to find hybridization? ›

Because hybridiztion is used to make atomic overlaps, knowledge of the number and types of overlaps an atom makes allows us to determine the degree of hybridization it has. In other words, you only have to count the number of bonds or lone pairs of electrons around a central atom to determine its hybridization.

How many sigma and pi bonds are in C2H2 hybridization? ›

Acetylene is said to have three sigma bonds and two pi bonds. The carbon-carbon triple bond in acetylene is the shortest (120 pm) and the strongest (965 kJ/mol) of the carbon-carbon bond types.

What is the hybridization of C2H2Cl2? ›

Ans. Hybridization of C is sp². The each Carbon atom in lewis structure of C2H2Cl2 are bonded by one double bond and two single bonds.

What is the hybridization of sp2? ›

The sp2 hybridization is the mixing of one s and two p atomic orbitals, which involves the promotion of one electron in the s orbital to one of the 2p atomic orbitals. The combination of these atomic orbitals creates three new hybrid orbitals equal in energy-level.

What is the hybridization of CH2O? ›

The molecular geometry of CH2O is AB3, and it has a trigonal planar structure with sp2 hybridization. The bond angles are 120 degrees, giving CH2O a trigonal planar geometry. The core atom of formaldehyde does not have any lone pairs of electrons, while the oxygen atom does have two lone pairs of electrons.

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